// SPDX-License-Identifier: GPL-2.0 /* gas-model.c */ /* gas compressibility model */ #include #include #include "dive.h" /* "Virial minus one" - the virial cubic form without the initial 1.0 */ #define virial_m1(C, x1, x2, x3) (C[0]*x1+C[1]*x2+C[2]*x3) /* * Z = pV/nRT * * Cubic virial least-square coefficients for O2/N2/He based on data from * * PERRY’S CHEMICAL ENGINEERS’ HANDBOOK SEVENTH EDITION * * with the lookup and curve fitting by Lubomir. * * The "virial" form of the compression factor polynomial is * * Z = 1.0 + C[0]*P + C[1]*P^2 + C[2]*P^3 ... * * and these tables do not contain the initial 1.0 term. * * NOTE! Helium coefficients are a linear mix operation between the * 323K and one for 273K isotherms, to make everything be at 300K. */ double gas_compressibility_factor(struct gasmix gas, double bar) { static const double o2_coefficients[3] = { -7.18092073703e-04, +2.81852572808e-06, -1.50290620492e-09 }; static const double n2_coefficients[3] = { -2.19260353292e-04, +2.92844845532e-06, -2.07613482075e-09 }; static const double he_coefficients[3] = { +4.87320026468e-04, -8.83632921053e-08, +5.33304543646e-11 }; int o2, he; double x1, x2, x3; double Z; o2 = get_o2(gas); he = get_he(gas); x1 = bar; x2 = x1*x1; x3 = x2*x1; Z = virial_m1(o2_coefficients, x1, x2, x3) * o2 + virial_m1(he_coefficients, x1, x2, x3) * he + virial_m1(n2_coefficients, x1, x2, x3) * (1000 - o2 - he); /* * We add the 1.0 at the very end - the linear mixing of the * three 1.0 terms is still 1.0 regardless of the gas mix. * * The * 0.001 is because we did the linear mixing using the * raw permille gas values. */ return Z * 0.001 + 1.0; } /* Compute the new pressure when compressing (expanding) volome v1 at pressure p1 bar to volume v2 * taking into account the compressebility (to first order) */ double isothermal_pressure(struct gasmix gas, double p1, int volume1, int volume2) { double p_ideal = p1 * volume1 / volume2 / gas_compressibility_factor(gas, p1); return p_ideal * gas_compressibility_factor(gas, p_ideal); } inline double gas_density(struct gasmix gas, int pressure) { int density = gas.he.permille * HE_DENSITY + gas.o2.permille * O2_DENSITY + (1000 - gas.he.permille - gas.o2.permille) * N2_DENSITY; return density * (double) pressure / gas_compressibility_factor(gas, pressure / 1000.0) / SURFACE_PRESSURE / 1000000.0; }